S.T.A.R.S.
Barry
Aconite's first impression of Barry Burton is that he's what is typically called a "teddy bear" personality, looks big and scary, but is soft and kind. He starts trying to bond with her father when he learns that Albert is a "single father who lost his wife to tragedy" over the fact they are both fathers. He treats Aconite with respect like he's speaking to another adult after learning that at age twelve, she was learning college-level general courses and two language classes, Spanish and Latin. She liked that.
Jill
Aconite's first impression of Jill Valentine is that she wants to be like her, a woman with no trouble telling people where they can put their opinions about the "fairer" sex. Aconite found it hilarious when Jill dropped a guy for grabbing her (Aconite) on the ass with a well-placed hit to the throat.
Aconite later asked Jill to teach her self-defense and lockpicking when she learned of it, much to the later horror of Chris, Brad, and Kevin when they learned that Aconite regularly picked the lockers of the team to keep her skills sharp, and fear of Captain Wesker when he found out that they had Playboy magazines in their lockers after Aconite asked him what the people in the magazine where doing which lead to Jill giving her the "talk" as Wesker didn't want to do it.
Rebecca
Aconite's first impression of Rebecca Chambers is that she's cute, like a kitten left out in the rain with big eyes and that she really needs to act more like Jill so the other male officers in the R.P.D. would stop hitting on her. Learning that Rebecca was the medic made Aconite ask to be taught basic first aid.
Chris
Aconite's first impression of Chris Redfield is that he's a puppy and crushing on her father. The man practically worshiped the ground Wesker walked on. This caused Aconite to call Chris "puppy" for the first year of his membership. He refused her request to teach her to be a sniper, the site of his captain holding up his gun and cocking it twenty feet behind his daughter in Chris' line of sight helped with that. Chris would be the first to call her "little sis."
Brad
Aconite's first impression of Brad Vickers is that he's an idiot, and he'd either get himself or the team killed. She did respect his talent for flying the helicopter, though. She nearly throttled him the first time he called her snowflake because of her pure white hair (it had turned entirely by the time she was nine), a nickname that would haunt her for years as everyone called her it at some point aside from her father.
Joseph
Aconite couldn't decide if she liked or hated Joseph Frost within the first five minutes of meeting him. He was equal parts annoying and amusing with his wisecracks about her hair and eyes. Most days, she would settle for ignoring it or throwing her S.T.A.R.S. combat knife at him intentionally missing but close enough for him to feel the breeze of the knife.
Jill and Wesker found it cute while everyone else mentally counted down the days until she stopped missing on purpose (she finally did nick his arm two years later in 1994 when he made a joke while she was on her monthly. Superhuman or not, periods are hell).
Enrico
Aconite like Enrico Marini, the pair were often found speaking in Spanish, and he was willing to help her with her accent when she couldn't quite say something right.
Kenneth
To Aconite, Kenneth Sullivan was a teddy bear alongside Barry and Edward. Still, she wasn't as fond of him because he treated her like a little kid who didn't understand what was being discussed and even brought coloring books for her thinking she was nine. Kenneth found a voodoo doll with his name on it pinned to Chris' dartboard with a knife the next day.
Forest
Forest Speyer was another who Aconite found annoying though not to the same degree as Joseph. She would never admit that she favored him because he just seemed to know when she was on her monthly without being told and would bring homemade cinnamon chocolate chip cookies just for her to make the torture bearable.
Edward
The third member of the "teddy bear trio" was Edward Dewey. Aconite like him because he didn't tease her about her hair, and when the chief would call all departments for a meeting, he would pick her up and put her on his shoulders so she could see. He would be the first to call her "little star," which her father picked up with a vengeance.
Richard
Aconite thought that Richard Aiken was an adorable puppy, like Chris, but instead of her father, it was Rebecca he was crushing on. The only problem was that both were utterly oblivious to the fact that they liked each other. Richard was the one to introduce her to what would become torture for anyone who pissed her off during her period, pranks. She would become a pranking demon on her period and sent three officers from homicide to the department's psychiatrist in a matter of days because the idiots pissed her off, they later had to be reassigned so that they wouldn't run into her because they would twitch if they saw her or they would scream and run. Everyone in S.T.A.R.S. found that amusing but made sure not to piss her off. Even Wesker wasn't safe from being pranked if he pissed off his daughter.
Kevin
Kevin Dooley was like Richard in that she saw him as a puppy, but he didn't have a crush on anyone, rather that he was just friendly like a puppy and wanted everyone to like him. She often fave him teats and called him "good boy" for doing things for either herself or her father.